KHCoP2O7.2H2O: a novel acidic pyrophosphate
Identifieur interne : 000A61 ( Main/Exploration ); précédent : 000A60; suivant : 000A62KHCoP2O7.2H2O: a novel acidic pyrophosphate
Auteurs : Mohamed Harcharras [Maroc] ; Kees Goubitz [Pays-Bas] ; Abdelaziz Ennaciri [Maroc] ; Hassane Assaaoudi [Maroc] ; Henk Schenk [Pays-Bas]Source :
- Acta crystallographica. Section C, Crystal structure communications [ 0108-2701 ] ; 2003.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
Potassium cobalt hydrogenpyrophosphate dihydrate, KHCo-P2O7.2H2O, crystallizes in the orthorhombic space group Pnma. This salt is isotypic with KHMP2O7.2H2O (M = Mn and Zn). The structure consists of alternating layers, built from HP2O73- acidic pyrophosphate groups and CoO6 octahedra, joined by potassium ions and bridging hydrogen bonds. The Co, K and water O atoms lie on mirror planes. The pyrophosphate group consists of two symmetry-related PO4 groups, with the bridging O atom on a mirror plane.
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream PascalFrancis, to step Corpus: 000231
- to stream PascalFrancis, to step Curation: 000064
- to stream PascalFrancis, to step Checkpoint: 000226
- to stream Main, to step Merge: 000A75
- to stream Main, to step Curation: 000A61
Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">KHCoP<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O: a novel acidic pyrophosphate</title>
<author><name sortKey="Harcharras, Mohamed" sort="Harcharras, Mohamed" uniqKey="Harcharras M" first="Mohamed" last="Harcharras">Mohamed Harcharras</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University the Tofail, BP 133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>14000 Kenitra</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Goubitz, Kees" sort="Goubitz, Kees" uniqKey="Goubitz K" first="Kees" last="Goubitz">Kees Goubitz</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratory for Crystallography, Institute of Molecular Chemistry, Faculty of Sciences, Universiteit van Amsterdam, Nieuwe Achtergracht 166</s1>
<s2>1018 WV Amsterdam</s2>
<s3>NLD</s3>
<sZ>2 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Pays-Bas</country>
<wicri:noRegion>1018 WV Amsterdam</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Ennaciri, Abdelaziz" sort="Ennaciri, Abdelaziz" uniqKey="Ennaciri A" first="Abdelaziz" last="Ennaciri">Abdelaziz Ennaciri</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University the Tofail, BP 133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>14000 Kenitra</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Assaaoudi, Hassane" sort="Assaaoudi, Hassane" uniqKey="Assaaoudi H" first="Hassane" last="Assaaoudi">Hassane Assaaoudi</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University the Tofail, BP 133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>14000 Kenitra</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Schenk, Henk" sort="Schenk, Henk" uniqKey="Schenk H" first="Henk" last="Schenk">Henk Schenk</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratory for Crystallography, Institute of Molecular Chemistry, Faculty of Sciences, Universiteit van Amsterdam, Nieuwe Achtergracht 166</s1>
<s2>1018 WV Amsterdam</s2>
<s3>NLD</s3>
<sZ>2 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Pays-Bas</country>
<wicri:noRegion>1018 WV Amsterdam</wicri:noRegion>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">INIST</idno>
<idno type="inist">03-0311020</idno>
<date when="2003">2003</date>
<idno type="stanalyst">PASCAL 03-0311020 INIST</idno>
<idno type="RBID">Pascal:03-0311020</idno>
<idno type="wicri:Area/PascalFrancis/Corpus">000231</idno>
<idno type="wicri:Area/PascalFrancis/Curation">000064</idno>
<idno type="wicri:Area/PascalFrancis/Checkpoint">000226</idno>
<idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000226</idno>
<idno type="wicri:Area/Main/Merge">000A75</idno>
<idno type="wicri:Area/Main/Curation">000A61</idno>
<idno type="wicri:Area/Main/Exploration">000A61</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">KHCoP<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O: a novel acidic pyrophosphate</title>
<author><name sortKey="Harcharras, Mohamed" sort="Harcharras, Mohamed" uniqKey="Harcharras M" first="Mohamed" last="Harcharras">Mohamed Harcharras</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University the Tofail, BP 133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>14000 Kenitra</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Goubitz, Kees" sort="Goubitz, Kees" uniqKey="Goubitz K" first="Kees" last="Goubitz">Kees Goubitz</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratory for Crystallography, Institute of Molecular Chemistry, Faculty of Sciences, Universiteit van Amsterdam, Nieuwe Achtergracht 166</s1>
<s2>1018 WV Amsterdam</s2>
<s3>NLD</s3>
<sZ>2 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Pays-Bas</country>
<wicri:noRegion>1018 WV Amsterdam</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Ennaciri, Abdelaziz" sort="Ennaciri, Abdelaziz" uniqKey="Ennaciri A" first="Abdelaziz" last="Ennaciri">Abdelaziz Ennaciri</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University the Tofail, BP 133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>14000 Kenitra</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Assaaoudi, Hassane" sort="Assaaoudi, Hassane" uniqKey="Assaaoudi H" first="Hassane" last="Assaaoudi">Hassane Assaaoudi</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University the Tofail, BP 133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>14000 Kenitra</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Schenk, Henk" sort="Schenk, Henk" uniqKey="Schenk H" first="Henk" last="Schenk">Henk Schenk</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratory for Crystallography, Institute of Molecular Chemistry, Faculty of Sciences, Universiteit van Amsterdam, Nieuwe Achtergracht 166</s1>
<s2>1018 WV Amsterdam</s2>
<s3>NLD</s3>
<sZ>2 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Pays-Bas</country>
<wicri:noRegion>1018 WV Amsterdam</wicri:noRegion>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Acta crystallographica. Section C, Crystal structure communications</title>
<title level="j" type="abbreviated">Acta crystallogr., Sect. C Cryst. struct. commun.</title>
<idno type="ISSN">0108-2701</idno>
<imprint><date when="2003">2003</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><title level="j" type="main">Acta crystallographica. Section C, Crystal structure communications</title>
<title level="j" type="abbreviated">Acta crystallogr., Sect. C Cryst. struct. commun.</title>
<idno type="ISSN">0108-2701</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Cobalt Pyrophosphates</term>
<term>Crystal structure</term>
<term>Experimental study</term>
<term>Hydrates</term>
<term>Hydrogen Pyrophosphates</term>
<term>Potassium Pyrophosphates</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Diffraction RX</term>
<term>Structure cristalline</term>
<term>Potassium Diphosphate</term>
<term>Hydrogène Diphosphate</term>
<term>Cobalt Diphosphate</term>
<term>Hydrate</term>
<term>6166F</term>
<term>KHCoP2O7</term>
<term>Co H K O P</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Potassium cobalt hydrogenpyrophosphate dihydrate, KHCo-P<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O, crystallizes in the orthorhombic space group Pnma. This salt is isotypic with KHMP<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O (M = Mn and Zn). The structure consists of alternating layers, built from HP<sub>2</sub>
O<sub>7</sub>
3- acidic pyrophosphate groups and CoO<sub>6</sub>
octahedra, joined by potassium ions and bridging hydrogen bonds. The Co, K and water O atoms lie on mirror planes. The pyrophosphate group consists of two symmetry-related PO<sub>4</sub>
groups, with the bridging O atom on a mirror plane.</div>
</front>
</TEI>
<affiliations><list><country><li>Maroc</li>
<li>Pays-Bas</li>
</country>
</list>
<tree><country name="Maroc"><noRegion><name sortKey="Harcharras, Mohamed" sort="Harcharras, Mohamed" uniqKey="Harcharras M" first="Mohamed" last="Harcharras">Mohamed Harcharras</name>
</noRegion>
<name sortKey="Assaaoudi, Hassane" sort="Assaaoudi, Hassane" uniqKey="Assaaoudi H" first="Hassane" last="Assaaoudi">Hassane Assaaoudi</name>
<name sortKey="Ennaciri, Abdelaziz" sort="Ennaciri, Abdelaziz" uniqKey="Ennaciri A" first="Abdelaziz" last="Ennaciri">Abdelaziz Ennaciri</name>
</country>
<country name="Pays-Bas"><noRegion><name sortKey="Goubitz, Kees" sort="Goubitz, Kees" uniqKey="Goubitz K" first="Kees" last="Goubitz">Kees Goubitz</name>
</noRegion>
<name sortKey="Schenk, Henk" sort="Schenk, Henk" uniqKey="Schenk H" first="Henk" last="Schenk">Henk Schenk</name>
</country>
</tree>
</affiliations>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/CobaltMaghrebV1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000A61 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 000A61 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Wicri/Terre |area= CobaltMaghrebV1 |flux= Main |étape= Exploration |type= RBID |clé= Pascal:03-0311020 |texte= KHCoP2O7.2H2O: a novel acidic pyrophosphate }}
This area was generated with Dilib version V0.6.32. |